Multiple types of Security Mode

I have a client that has 2 types of devices on their wired LAN.

PC's that are part of a Windows AD domain

Thin Clients that are not part of the the domain.

They would like for the PC's to use some sort of SSO, and for the Thin Clients to be challenged with a Captive Portal authentication.

Is this possible in FIOS 5.2? Thanks!